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1 article(s) from Talukdar, Ranadeep

Catalyzed and uncatalyzed procedures for the syntheses of isomeric covalent multi-indolyl hetero non-metallides: an account

Ranadeep Talukdar

Beilstein J. Org. Chem. 2021, 17, 2102–2122, doi:10.3762/bjoc.17.137

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Graphical Abstract

Scheme 1: Synthesis of 2,2’-bis(indole)borinic ester 3.

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Scheme 2: Synthesis of 2,2’-bisindole NHC·boranes by an S_EAr mechanism.

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Scheme 3: Syntheses of indolyl amines through Buchwald–Hartwig cross coupling.

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Scheme 4: Synthesis of 3,3’-bis(indolyl) ethers.

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Scheme 5: C–H silylation of indoles.

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Scheme 6: n-BuLi-mediated syntheses of bis(indol-3-yl)silanes.

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Scheme 7: Acid-catalyzed syntheses of bis(indol-3-yl)silanes and mechanisms.

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Scheme 8: B(C₆F₅)₃ and Al(C₆F₅)₃-catalyzed syntheses of bis(indol-3-yl)silanes reported by Han.

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Scheme 9: Base-mediated syntheses of bis and tris(indol-2-yl)phosphines.

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Scheme 10: Synthesis of bis(indol-2-yl)sulfides using SL₂-type reagents.

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Scheme 11: Synthesis of 2,3’- and 2,2’-bis(indolyl)sulfides using disulfides as substrates.

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Scheme 12: Synthesis of diindol-2-ylsulfide (84) from 2-iodoindole (92) and thiourea.

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Scheme 13: Synthesis of bis(indol-3-yl)sulfides using N-silylated 3-bromoindole 93.

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Scheme 14: Fischer indole synthesis of bis(indol-3-yl)sulfides using thio diketones.

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Scheme 15: Oxidative synthesis of bis(indol-3-yl)sulfides using indoles and elemental sulfur.

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Scheme 16: Synthesis of bis(indol-3-yl)sulfides using sulfoxides as sulfur source.

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Scheme 17: Syntheses of bis(indol-2-yl)selanes.

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Scheme 18: Syntheses of bis(indol-3-yl)selanes.

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Scheme 19: Synthesis of bis(indol-2-yl)tellane 147.

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Scheme 20: Synthesis of tris(indolyl)borane 154.

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Scheme 21: Synthesis of bis(indol-4-yl)amines 159.

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Scheme 22: Synthesis of bis(indol-5-yl)amines.

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Scheme 23: Synthesis of 6,5’/6,6’-bis(indolyl)amines.

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Scheme 24: Synthesis of potent HIV-inhibitors 6,6’-bis(indolyl) ethers.

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Scheme 25: Synthesis of bis(indol-7-yl) ether.

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Scheme 26: Synthesis of di(indol-5-yl)sulfide (183).

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Scheme 27: Syntheses of 2,2’-diformyl-7,7’-bis(indolyl)selenides.

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Review

Published 19 Aug 2021

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